基于信号重构的一种系统仿真方法

本文根据信号重构的思想，提出了一种系统仿真方法。该方法是对时域矩阵仿真方法的扩展，即保留了时域矩阵方法快速性的特点，又提高了仿真精度。文中还对该方法的截断误差做出了估计，并证明了该方法的收敛性。最后，通过仿真例子说明了该方法的有效性。     

XPS研究多壁碳纳米管的阳极氧化处理效果

采用阳极氧化法对多壁碳纳米管（MWNTs）进行表面处理以提高其表面极性官能团含量。研究了不同电解参数对MWNTs处理结果的影响，采用X射线光电子能谱对处理前后的MWNTs的表面特征进行了分析。结果表明，经阳极氧化处理后，MWNTs表面氧原子摩尔分数与极性官能团总量均有不同程度增加。通电量和碱性电解质的电导率（物质的量浓度）是阳极氧化处理过程的主要影响因素，MWNTs表面极性官能团总量的增加可以归结为羟基的增加和羰基的减少，另外还探讨了可能的氧化反应机理。     

THz time-domain spectroscopy of amino acids

The optical characteristics of four kinds of amino acids （tyrosine, arginine, histidine and glutamine） filled with nitrogen at room temperature were studied by THz time-domain spectroscopy （THz-TDS）. Well-resolved absorption and refractive spectrums between 0.I and 2.8 THz were obtained based on the physical model for extracting the optical parameters of materials in THz range. The results not only fill up the spectra gap of amino acids in far-infrared range, supply data for amino acid molecular identification and conformation analysis, but also demonstrate significantly potential to promote the research and application of biological materials in bio-chemical and medical fields by THz-TDS.     

苯丙氨酸的太赫兹光谱测试与理论研究

采用太赫兹时域光谱（THz-TDS）技术,在室温氮气环境下对固态苯丙氨酸进行了光谱测试,获得了样品在THz波段的特征吸收谱,发现苯丙氨酸样品在有效光谱范围（0.2～2.2 THz）内有两个明显的特征吸收峰,分别位于1.23和1.99THz处.用从头算理论,在HF/6-31G水平下对苯丙氨酸分子进行结构优化和频率计算,得到了样品在0.1～10 THz的振动频谱.在有效光谱范围内,理论计算结果与实验相互对应且符合较好,同时根据计算结果对实验中特征吸收的振动模式进行了指认.     

TiO2薄膜的光电催化性能及电化学阻抗谱研究

用直流磁控溅射法在钛网上制备了TiO2薄膜催化剂,采用电化学阻抗谱（EIS）对其阻抗谱特征进行了表征.同时以偶氮酸性红溶液为模型污染物,验证了此工作电极在不同条件下的光电催化活性与阻抗谱之间的关系.研究表明：光电催化实验中TiO2薄膜在同时有紫外光和外加阳极偏压的情况下,有效实现电子-空穴分离,具有最好的催化活性;最佳的外加阳极偏压值为0.3V;其EIS Nyquist图上阻抗环半径也在此时最小,最容易发生反应,与光电催化实验结果一致.     

腔衰荡光谱技术的理论分析

腔衰荡光谱技术是一种新型的光谱检测方法,由于该技术具有吸收光程长,不受光源强度起伏影响的特点,因而受到国内外的广泛重视,已被应用于探测分子及原子体系。本文主要分析腔衰荡光谱技术的原理、相关核心部件的选择及注意事项,为下一步仪器的研制奠定基础。     

深能级测量中的软件技术

由微计算机通过AD/DA变换器产生深能级测量中必须的脉冲和偏压控制信号以及温度控制信号,并对瞬态电容和样品温度进行测量,可在一次温度扫描过程中获得一组对应于不同的测量率窗的深能级信号曲线,从而获得深能级的全部参数。采用指数式变化的相关加权系数可以大大提高测量的灵敏度。通过计算可求得最佳的加权系数。用高阶相关的方法可以改善测量谱峰的分辨能力。机器语言子程序可大大提高瞬态电容的测量速率并可保证严格的时序。各个测量点的延迟时间可在0.5ms到数十秒的范围内调节。     

基于压缩传感的单点太赫兹成像

太赫兹（Terahertz,1THz=1012Hz）波通常是指频率在0．1THz-10THz（波长在3mm-30urn）范围内的电磁辐射．随着THz相关技术的发展,THz成像技术在更多领域将显示其更大的实用价值．在本文中,我们对物体进行单点THz成像,此系统的核心是一个单像素探测器和一系列随机掩膜板．成像的方式是基于压缩传感理论（cs）．此理论主要包括信号稀疏表示,编码测量和重建算法三部分．其核心思想是将压缩与采样合并进行,首先采集图像的非自适应线性投影（测量值）,然后根据相应重构算法由测量值重构原始图像．此系统通过测量图像和单一掩膜板的内积来得到单-THz强度值,最后得到一系列与掩膜板数目相同的测量值．CS理论可以从比N2少得多的测量值中来重建一幅NxN的图像,从而缩短成像时间,这种单点成像系统消除了对物体或THz波束进行光栅扫描的必要,不但提高了成像速度,而且保持了单像素探测的高灵敏度．我们利用连续THz波源一返波振荡器来进行实验并得到了初步实验结果．     

Characterization of cocrystals formed by grinding amino acids through terahertz time-domain spectroscopy

In this paper,we used terahertz time-domain spectroscopy(THz-TDS)over a range of 0.3–2.5 THz to investigate the formation of solid-state cocrystals of amino acids,formed by grinding mixtures of two different kinds of amino acids.For comparison,we prepared dual-layer samples,combined by pressing two single-component pellets together without grinding.In the ground-mixture samples,some extra absorption peaks appeared,different from the characteristic peaks of the pure components,but these peaks did not appear in the dual-layer samples.Thus,these extra absorption peaks in the THz range are unique features of cocrystals.From our results,we believe that THz-TDS is a promising technique to characterize cocrystals.     

An investigation on terahertz response in electro-optic crystals excited at 1.03 lm wavelength

We theoretically investigate terahertz(THz)emission and detection from h110i-oriented electro-optic(EO) crystals adapted for Yb-doped femtosecond pulse laser.According to the principles of phase-matching condition, the dispersion relation between optical velocity and THz pulse,THz absorption spectra, and coherence lengths of CdTe, GaP,and GaAs crystals below the phonon resonant frequency are calculated correspondingly. The optical rectification and EO sampling process of above crystals with the same thickness of0.1 mm are simulated. As a consequence, we found that the optimal emission frequency of CdTe is at 2.65 THz, however,it reaches 6.56 THz of GaAs and 4.77 THz of GaP. With the help of frequency response function, the calculated cut-off frequency of CdTe is only 3.45 THz, while GaAs and GaP achieve 7.15 and 6.37 THz correspondingly. Finally, the EO sampling sensitivity of GaAs is higher than CdTe and GaP when the crystal's thickness exceeds 1.58 mm. The strong THz absorption of CdTe saturates distinctly the EO sampling sensitivity with its thickness increasing.